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Mesoporous silicas tethered with anions as quasi-solid electrolytes for lithium-metal batteries.

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Mesoporous silicas tethered with anions were developed as quasi-solid electrolytes for Li-metal batteries. The high grafted density of trifluoromethylsulfonyl (-NTf-) groups and their uniformly distributed negative charge endow MCM41-NLiTf with… Click to show full abstract

Mesoporous silicas tethered with anions were developed as quasi-solid electrolytes for Li-metal batteries. The high grafted density of trifluoromethylsulfonyl (-NTf-) groups and their uniformly distributed negative charge endow MCM41-NLiTf with a room temperature single Li-ion conductivity of up to 2.4 × 10-4 S cm-1, which enables stable cycling of LFP‖Li batteries.

Keywords: mesoporous silicas; metal batteries; quasi solid; tethered anions; solid electrolytes; silicas tethered

Journal Title: Chemical communications
Year Published: 2022

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