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Direct access to thieno[3,4-b]thiophenes via elemental sulfur-promoted sulfurative tetramerization of acetophenones.

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Thieno[3,4-b]thiophene cores could be conveniently obtained via one-pot sulfurative tetramerization of acetophenones using a ternary system comprised of elemental sulfur, a base and DMSO under simple heating conditions. The structure… Click to show full abstract

Thieno[3,4-b]thiophene cores could be conveniently obtained via one-pot sulfurative tetramerization of acetophenones using a ternary system comprised of elemental sulfur, a base and DMSO under simple heating conditions. The structure of the products was verified by X-ray crystallography.

Keywords: sulfurative tetramerization; direct access; tetramerization acetophenones; elemental sulfur; access thieno

Journal Title: Chemical communications
Year Published: 2022

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