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Perovskite chemical gardens: highly fluorescent microtubes from self-assembly and ion exchange.

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We report the shape-preserving conversion of self-assembled CaCO3 microtubes to PbCO3 and MAPbBr3 perovskite. The first step induces the growth of cerussite needles on the outer surface. When further converted,… Click to show full abstract

We report the shape-preserving conversion of self-assembled CaCO3 microtubes to PbCO3 and MAPbBr3 perovskite. The first step induces the growth of cerussite needles on the outer surface. When further converted, these hedgehog-like structures become fluorescent. Additional spatial control of the process yields Janus tubes of CaCO3 and perovskite segments.

Keywords: fluorescent microtubes; chemical gardens; microtubes self; highly fluorescent; gardens highly; perovskite chemical

Journal Title: Chemical communications
Year Published: 2022

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