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Zn(II)-MOF derived N-doped carbons achieve marked ORR activity in alkaline and acidic media.

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A highly efficient metal-free N-doped carbon electrocatalyst toward oxygen reduction was obtained by one-pot pyrolysis of a single Zn(II)-MOF with mixed azolate and terephthalate ligands, demonstrating E1/2 of 0.88 V… Click to show full abstract

A highly efficient metal-free N-doped carbon electrocatalyst toward oxygen reduction was obtained by one-pot pyrolysis of a single Zn(II)-MOF with mixed azolate and terephthalate ligands, demonstrating E1/2 of 0.88 V (vs. RHE) in 0.1 M KOH, and 0.79 V (vs. RHE) in 0.5 M H2SO4. It represents one of the best metal-free N-doped carbon electrocatalysts for the acidic ORR.

Keywords: mof derived; carbons achieve; derived doped; achieve marked; doped carbons; marked orr

Journal Title: Chemical communications
Year Published: 2022

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