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We report "flexibility constants"-a conceptual analog to metal-ligand stability constants-of UiO-66, the prototypical "stable" MOF, across a wide temperature range in both vacuum and in the presence of typical guest… Click to show full abstract
We report "flexibility constants"-a conceptual analog to metal-ligand stability constants-of UiO-66, the prototypical "stable" MOF, across a wide temperature range in both vacuum and in the presence of typical guest solvents. With these data, we extract key thermodynamic parameters governing the reversible bond equilibrium and demonstrate that guest molecules strongly favor the reversible dissociation of MOF metal-linker bonds.
Keywords:
guest dependent;
mof;
stable mof;
dependent bond;
flexibility
Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!