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Time-resolved EPR revealed C(sp3)-H activation through a photo-enhanced phthalimide-N-oxyl (PINO) radical.

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The time-resolved electron paramagnetic resonance (EPR) technique under operando photochemical conditions as an efficient strategy to investigate the fast formation of abundant long-lived PINO radicals (t1/2 = 204 s) and… Click to show full abstract

The time-resolved electron paramagnetic resonance (EPR) technique under operando photochemical conditions as an efficient strategy to investigate the fast formation of abundant long-lived PINO radicals (t1/2 = 204 s) and their activation of the C(sp3)-H process has been researched. This developed method offers a pathway for investigating the properties and tracking the transformations of radical species in the photoredox reaction process.

Keywords: epr revealed; time; resolved epr; time resolved; pino; activation

Journal Title: Chemical communications
Year Published: 2022

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