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Surface fluorine preservation dependence of Ti3C2Tx MXene for high electrochemical properties in ionic liquid electrolytes.

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We identified the contribution of -CF3 terminations to the Ti3C2Tx surface structure when ethanol and water were used as solvents during delamination through experimental and computational studies. Ethanol-treated -CF3-terminated Ti3C2Tx… Click to show full abstract

We identified the contribution of -CF3 terminations to the Ti3C2Tx surface structure when ethanol and water were used as solvents during delamination through experimental and computational studies. Ethanol-treated -CF3-terminated Ti3C2Tx achieves better prevention of nanoflake aggregation, hydrophobicity, and small size, enabling enhanced capacitive properties in ionic liquid compared to water-treated Ti3C2Tx in aqueous and ionic liquid electrolytes.

Keywords: fluorine preservation; liquid electrolytes; surface fluorine; properties ionic; ionic liquid; liquid

Journal Title: Chemical communications
Year Published: 2023

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