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Catalyst- and additive-free syntheses of rhodanine and S-alkyl dithiocarbamate derivatives from sulfoxonium ylides.

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An efficient catalyst- and additive-free facile access to rhodanine and S-alkyl dithiocarbamate derivatives via multi-component reaction of amines, CS2 and α-ester sulfoxonium ylides in methanol has been described. The new… Click to show full abstract

An efficient catalyst- and additive-free facile access to rhodanine and S-alkyl dithiocarbamate derivatives via multi-component reaction of amines, CS2 and α-ester sulfoxonium ylides in methanol has been described. The new synthetic methods offer excellent synthetic prospects for several functionalized rhodanines and S-alkyl dithiocarbamates with simple operational procedures.

Keywords: dithiocarbamate derivatives; alkyl dithiocarbamate; additive free; rhodanine alkyl; catalyst additive; sulfoxonium ylides

Journal Title: Chemical communications
Year Published: 2023

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