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Salicylaldehydate coordinated two-dimensional-conjugated metal-organic frameworks.

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A novel class of copper-based 2D-c-MOF was synthesized from 1,3,5-triformylphloroglucinol using green mechano-chemistry. Herein, metal coordination with the salicylaldehyde functional moiety was explored for the first time in MOFs. Moreover,… Click to show full abstract

A novel class of copper-based 2D-c-MOF was synthesized from 1,3,5-triformylphloroglucinol using green mechano-chemistry. Herein, metal coordination with the salicylaldehyde functional moiety was explored for the first time in MOFs. Moreover, an intrinsic semiconductive copper-based SA-MOF thin film was fabricated using an in situ salt-free method at room temperature.

Keywords: coordinated two; two dimensional; dimensional conjugated; conjugated metal; salicylaldehydate coordinated; metal

Journal Title: Chemical communications
Year Published: 2023

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