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Topological entrapment of macromolecules during the formation of metal-organic framework.

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Here we present our preliminary results on a novel approach to encapsulate large guest molecules in nanoporous materials, metal-organic frameworks (MOFs), via a newly discovered in situ crystal formation. This… Click to show full abstract

Here we present our preliminary results on a novel approach to encapsulate large guest molecules in nanoporous materials, metal-organic frameworks (MOFs), via a newly discovered in situ crystal formation. This method has exciting prospects not only in the design of new organic/inorganic hybrids but also in capturing and separating molecules that are significantly larger than the actual pore size of the host MOF.

Keywords: topological entrapment; organic framework; metal organic; entrapment macromolecules; macromolecules formation; formation metal

Journal Title: Chemical communications
Year Published: 2023

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