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Here, an efficient Minisci reaction of heteroarenes and unactivated C(sp3)-H alkanes was achieved using an inexpensive FeCl3 as a photocatalyst. The photogenerated chlorine radical contributed to the HAT of C-H… Click to show full abstract
Here, an efficient Minisci reaction of heteroarenes and unactivated C(sp3)-H alkanes was achieved using an inexpensive FeCl3 as a photocatalyst. The photogenerated chlorine radical contributed to the HAT of C-H and subsequently initiated this reaction. Surprisingly, salt water and even seawater can act as a chlorine radical source, which provided an enlightening idea for future organic synthesis methods.
Keywords:
chlorine radical;
heteroarenes unactivated;
unactivated sp3;
reaction;
reaction heteroarenes;
minisci reaction
Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!