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Minisci reaction of heteroarenes and unactivated C(sp3)-H alkanes via a photogenerated chlorine radical.

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Here, an efficient Minisci reaction of heteroarenes and unactivated C(sp3)-H alkanes was achieved using an inexpensive FeCl3 as a photocatalyst. The photogenerated chlorine radical contributed to the HAT of C-H… Click to show full abstract

Here, an efficient Minisci reaction of heteroarenes and unactivated C(sp3)-H alkanes was achieved using an inexpensive FeCl3 as a photocatalyst. The photogenerated chlorine radical contributed to the HAT of C-H and subsequently initiated this reaction. Surprisingly, salt water and even seawater can act as a chlorine radical source, which provided an enlightening idea for future organic synthesis methods.

Keywords: chlorine radical; heteroarenes unactivated; unactivated sp3; reaction; reaction heteroarenes; minisci reaction

Journal Title: Chemical communications
Year Published: 2023

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