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Extending the Hammett correlation to mechanochemical reactions.

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Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating… Click to show full abstract

Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical-organic chemistry could be transferable to ball milling reactions in the solid state.

Keywords: mechanochemical reactions; extending hammett; chemistry; correlation mechanochemical; correlation; hammett correlation

Journal Title: Chemical communications
Year Published: 2023

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