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FA cation replenishment-induced second growth of printed MA-free perovskites for efficient solar cells and modules.

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Printing is one industrially compatible scalable method for the preparation of perovskite thin films but suffers from a low nucleation rate that causes an inferior crystal quality. In this work,… Click to show full abstract

Printing is one industrially compatible scalable method for the preparation of perovskite thin films but suffers from a low nucleation rate that causes an inferior crystal quality. In this work, we applied a slot-die coating method to deposit a MA-free perovskite thin film with a subsequently introduced FA+ replenishment to induce a second growth and prepare a FA-rich film. As a result, the inverted perovskite mini-module reached an efficiency of 17.56% with an aperture area of 60.84 cm2.

Keywords: cation replenishment; induced second; second growth; growth; growth printed; replenishment induced

Journal Title: Chemical communications
Year Published: 2023

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