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Homoleptic Cr(III) complexes containing anionic tridentate 1,8-(bisoxazolyl)carbazolide ligands are phosphorescent in deaerated solutions with peak maxima in the range of 813-845 nm. The ligand carbon-centred chirality has been transferred to… Click to show full abstract
Homoleptic Cr(III) complexes containing anionic tridentate 1,8-(bisoxazolyl)carbazolide ligands are phosphorescent in deaerated solutions with peak maxima in the range of 813-845 nm. The ligand carbon-centred chirality has been transferred to the helical chirality of the complexes and hence induced circularly polarized NIR-emissions with dissymmetry factor in the scale of 2.0 × 10-3.
Keywords:
infrared phosphorescence;
iii complexes;
near infrared;
polarized near;
circularly polarized
Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
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recommendations!