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Partial quaternization promoted metal-organic frameworks for efficient photocatalytic removal of chromium(VI).

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A one-step strategy is applied to partially quaternize the ligand of UiO-66-NH2, and the resultant UiO-66-N(CH3)3+ showed greatly improved photocatalytic performance for Cr(VI) reduction, with the apparent reaction rate constant… Click to show full abstract

A one-step strategy is applied to partially quaternize the ligand of UiO-66-NH2, and the resultant UiO-66-N(CH3)3+ showed greatly improved photocatalytic performance for Cr(VI) reduction, with the apparent reaction rate constant k increasing by 8.3 times. This strategy could be used to effectively promote the performance of other MOFs-NH2, demonstrating general applicability.

Keywords: promoted metal; quaternization promoted; partial quaternization; organic frameworks; frameworks efficient; metal organic

Journal Title: Chemical communications
Year Published: 2023

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