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Cs[B3O3F2(OH)2]: discovery of a hydroxyfluorooxoborate guided by selective organic-inorganic transformation.

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Selective transformation between organic and inorganic systems is crucial but still remains a challenge. Herein, we demonstrated that selective organic-inorganic transformation is a simple but effective strategy to find new… Click to show full abstract

Selective transformation between organic and inorganic systems is crucial but still remains a challenge. Herein, we demonstrated that selective organic-inorganic transformation is a simple but effective strategy to find new hydroxyfluorooxoborates. By replacing the [Ph4P]/[Ph3MeP] organic cations with Cs atoms, a new hydroxyfluorooxoborate Cs[B3O3F2(OH)2] with three-membered [B3O3F2(OH)2] clusters was synthesized. Theoretical analysis confirmed the effects of different components in the lattice of reported structure on the optical properties.

Keywords: hydroxyfluorooxoborate; inorganic transformation; organic inorganic; selective organic; b3o3f2; transformation

Journal Title: Chemical communications
Year Published: 2023

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