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The luminescence of single crystals of (TBA)PbCl3, (TBA)2Sb2Cl8, (TBA)3Bi2Cl9 and (TBA)SnCl5·2EtOH (TBA = tetrabutylammonium, EtOH = Ethanol) synthsized were assigned distinctively to the centres of self-trapped excitons (STEs), TBA+, TBA+… Click to show full abstract
The luminescence of single crystals of (TBA)PbCl3, (TBA)2Sb2Cl8, (TBA)3Bi2Cl9 and (TBA)SnCl5·2EtOH (TBA = tetrabutylammonium, EtOH = Ethanol) synthsized were assigned distinctively to the centres of self-trapped excitons (STEs), TBA+, TBA+ and co-emission of STEs and TBA+. This work demonstrates that organic cations without benzene or aromatic rings can also be used as the sole luminescence centres for metal halides.
Keywords:
tetrabutylammonium metal;
tba;
metal chlorides;
photophysical properties;
chlorides different;
properties tetrabutylammonium
Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2023
Link to full text (if available)
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recommendations!