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Visible-light-induced Csp3-H functionalization of glycine derivatives by cerium catalysis.

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A Ce(III)-catalyzed, visible-light-induced aerobic oxidative dehydrogenative coupling/aromatization reaction between glycine derivatives and alkenes has been developed, which provides an efficient approach for the synthesis of quinoline derivatives and post-modification of… Click to show full abstract

A Ce(III)-catalyzed, visible-light-induced aerobic oxidative dehydrogenative coupling/aromatization reaction between glycine derivatives and alkenes has been developed, which provides an efficient approach for the synthesis of quinoline derivatives and post-modification of oligopeptides containing glycine residues under mild conditions without the need for external photosensitizers.

Keywords: light induced; induced csp3; glycine; glycine derivatives; visible light

Journal Title: Chemical communications
Year Published: 2023

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