LAUSR

The N-heterocyclic olefin (NHO) ImMe4CH2 (2) (ImMe4CH2 = (MeCNMe)2CCH2) was employed for the synthesis of the titanium complex 3 derived from an NHO ligand precursor. By reacting 2 with the bis(π-η5:σ-η1-pentafulvene)titanium complex 1a, the terminal ylidic methylene unit of 2 is deprotonated by the quaternary exocyclic carbon atom of one pentafulvene ligand of 1a yielding the titanium complex 3 which bears an anionic NHO ligand (ImMe4CH-). 3 was characterized by NMR spectroscopy, single crystal X-ray diffraction and quantum chemical calculations. The latter highlight that 3 is best described as a titanium vinyl complex with significant contribution of the titanium alkylidene resonance structure.