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Gas-phase deposition of di- and tetra-lithium salts of 2,5-dihydroxyterephthalic acid.

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Thin films of two ambipolar lithium-organic electrode materials, Li2DHTP and Li4DHTP, are grown from gaseous precursors, Li(thd) (tetramethyl heptanedione) and DHTP (dihydroxyterephthalic acid). These precursors are pulsed into the reactor… Click to show full abstract

Thin films of two ambipolar lithium-organic electrode materials, Li2DHTP and Li4DHTP, are grown from gaseous precursors, Li(thd) (tetramethyl heptanedione) and DHTP (dihydroxyterephthalic acid). These precursors are pulsed into the reactor in a sequential manner like in atomic/molecular layer deposition, but the reaction product, i.e. the di- or the tetra-lithium salt, is controlled by adjusting the precursor pulse lengths.

Keywords: gas phase; dihydroxyterephthalic acid; phase deposition; lithium; tetra lithium

Journal Title: Dalton transactions
Year Published: 2022

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