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Formation of NiFe-MOF nanosheets on Fe foam to achieve advanced electrocatalytic oxygen evolution.

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2D bimetal metal organic frameworks (MOFs) are recognized as one of the most promising electrocatalysts for the oxygen evolution reaction (OER). Herein, a facile approach was proposed to construct NiFe-MOF… Click to show full abstract

2D bimetal metal organic frameworks (MOFs) are recognized as one of the most promising electrocatalysts for the oxygen evolution reaction (OER). Herein, a facile approach was proposed to construct NiFe-MOF nanosheets on Fe foam (FF). As a self-supporting electrode, the NiFe-MOF/FF electrode shows impressive electrocatalytic OER performance. Specifically, it exhibits an ultra-low overpotential of 216 mV to reach a current density of 50 mA cm-2, and outstanding stability (beyond 50 h at 200 mA cm-2). The excellent performances of NiFe-MOF/FF arise from the highly exposed active centers, the excellent conductivity, and the synergy effect between Ni and Fe. This research provides a promising strategy for the synthesis of multi-metal MOFs as high-efficiency electrocatalysts.

Keywords: oxygen evolution; formation nife; nife mof; nanosheets foam; mof nanosheets; foam achieve

Journal Title: Dalton transactions
Year Published: 2022

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