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Two lead borate-nitrates Pb6O4(BO3)(NO3) and Pb6O2(BO3)2(NO3)F were obtained by the high-temperature flux method. Interestingly, their crystal structure consists of anion-centered [OPb4] tetrahedra and π-conjugated BO3 and NO3 units. The first… Click to show full abstract
Two lead borate-nitrates Pb6O4(BO3)(NO3) and Pb6O2(BO3)2(NO3)F were obtained by the high-temperature flux method. Interestingly, their crystal structure consists of anion-centered [OPb4] tetrahedra and π-conjugated BO3 and NO3 units. The first principles calculations indicate that both compounds show large birefringence.
Keywords:
lead borate;
borate nitrates;
opb4 tetrahedra;
centered opb4;
two lead;
anion centered
Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!