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Two-dimensional coordination polymers with high proton conductivity and ultrafast highly efficient molecular sieving constructed by the structural inductive effect.

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A family of unique 2D-layered Cu-based coordination polymers (abbreviated as HNNU-1α, 1β and 1γ) with different halide anions were successfully constructed using a zwitterion pyridiniumolate as the structural inductive agent… Click to show full abstract

A family of unique 2D-layered Cu-based coordination polymers (abbreviated as HNNU-1α, 1β and 1γ) with different halide anions were successfully constructed using a zwitterion pyridiniumolate as the structural inductive agent (SIA). More importantly, we found that the laminates of HNNU-1α exhibit ultrafast highly-efficient molecular sieving in a water system, and HNNU-1α to 1γ display a good proton conductivity of ca. 2.2 × 10-2, 4.9 × 10-5, and 3.0 × 10-4 S cm-1 at 90 °C and 98% relative humidity (RH), respectively.

Keywords: molecular sieving; ultrafast highly; coordination polymers; structural inductive; efficient molecular; highly efficient

Journal Title: Dalton transactions
Year Published: 2022

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