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Facile C-N bond cleavage of primary aliphatic amines by (salen)ruthenium(VI) nitrido complexes.

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We report the first example of oxidative cleavage of the strong C-N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C-N cleavage… Click to show full abstract

We report the first example of oxidative cleavage of the strong C-N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C-N cleavage reaction comes from the formation of stable NN after the initial coupling of the amine N and the nitrido ligand.

Keywords: cleavage; bond cleavage; ruthenium nitrido; facile bond

Journal Title: Dalton transactions
Year Published: 2022

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