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Identification of complexes of Nd(III) with dithiophosphinic acids verifying the difference in complexation between Ln(III) and An(III).

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Five complex species of Nd(III) with HA have been spectroscopically and compositionally identified as NdA3, NdA3(HA), NdA3(HA)H2O, NdA3(H2O)3, and Nd(H2O)23·3A (HA, bis(2,4,4-trimethylpentyl)dithiophosphinic acid) with the help of X-ray diffraction analysis… Click to show full abstract

Five complex species of Nd(III) with HA have been spectroscopically and compositionally identified as NdA3, NdA3(HA), NdA3(HA)H2O, NdA3(H2O)3, and Nd(H2O)23·3A (HA, bis(2,4,4-trimethylpentyl)dithiophosphinic acid) with the help of X-ray diffraction analysis on single crystals of Nd(H2O)9·H2O·3B (HB = bis(iso-butyl)dithiophosphinic acid.

Keywords: acids verifying; iii dithiophosphinic; iii; complexes iii; dithiophosphinic acids; identification complexes

Journal Title: Dalton transactions
Year Published: 2022

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