Photo from wikipedia
Spectroscopic and computational examination of the neutral tris-dioxolene complex [V(dbcat)3] (dbcat2- = 3,6-di-tert-butylcatecholate) reveals a Class III mixed-valent ground state. The radical is stabilised by delocalisation across the ligands mediated… Click to show full abstract
Spectroscopic and computational examination of the neutral tris-dioxolene complex [V(dbcat)3] (dbcat2- = 3,6-di-tert-butylcatecholate) reveals a Class III mixed-valent ground state. The radical is stabilised by delocalisation across the ligands mediated by the energy matched d orbital manifold of the V(V) centre. This electronic structure is compared to the tris-dithiolene and tris-diimine analogues that possess V(IV) and V(II) ions, respectively.
Keywords:
tris chelates;
redox active;
vanadium tris;
electronic versatility;
chelates redox;
versatility vanadium
Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!