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Hybrid lanthanide double-deckers based on calixarene and polyoxometalate units.

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Complementarity of calixarene (H2L) and polyoxometalate ligands results in the first organic-inorganic [MIIIL{Mo5O13(OMe)4(NO)}]2- (M = Y, Gd and Dy) hybrid, directing the formation of a distorted square-antiprismatic MO8 ligand field… Click to show full abstract

Complementarity of calixarene (H2L) and polyoxometalate ligands results in the first organic-inorganic [MIIIL{Mo5O13(OMe)4(NO)}]2- (M = Y, Gd and Dy) hybrid, directing the formation of a distorted square-antiprismatic MO8 ligand field and resulting in slow relaxation of the magnetisation for the Dy derivative.

Keywords: deckers based; based calixarene; lanthanide double; double deckers; hybrid lanthanide; calixarene polyoxometalate

Journal Title: Dalton transactions
Year Published: 2022

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