LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Supramolecular organometallic chemistry: the platinum(IV) paradigm.

Photo from wikipedia

Supramolecular chemistry and the chemistry of alkyl derivatives of the transition metals are both topics of considerable current interest, but the combination of the two fields is still underdeveloped. The… Click to show full abstract

Supramolecular chemistry and the chemistry of alkyl derivatives of the transition metals are both topics of considerable current interest, but the combination of the two fields is still underdeveloped. The challenges are, in large part, experimental in nature. For example, the self-assembly of molecules in supramolecular chemistry often relies on intermolecular hydrogen bonding, but most alkyl-transition metal bonds are cleaved by the protic groups used in hydrogen bond formation. Alkyl-platinum(IV) bonds are inert to protonolysis or attack by other electrophiles under mild conditions, and this has allowed an extensive supramolecular chemistry of organoplatinum(IV) complexes to be developed, as outlined in this perspective review. Highlights include a zeolitic structure, a polyrotaxane, a double helix, a nanotube structure and an example of spontaneous resolution to form a chiral sheet structure.

Keywords: chemistry platinum; chemistry; supramolecular chemistry; platinum; supramolecular organometallic; organometallic chemistry

Journal Title: Dalton transactions
Year Published: 2022

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.