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Recent advances of mesoionic N-heterocyclic olefins.

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This Perspective article highlights the recent development of mesoionic N-heterocyclic olefins (mNHOs), where the exo-cyclic olefinic carbon is not bonded to strongly electron-withdrawing groups. The unquenched basicity and nucleophilicity of… Click to show full abstract

This Perspective article highlights the recent development of mesoionic N-heterocyclic olefins (mNHOs), where the exo-cyclic olefinic carbon is not bonded to strongly electron-withdrawing groups. The unquenched basicity and nucleophilicity of the exo-cyclic olefinic carbon make mNHOs strong σ-donors and enable unique reactivity patterns.

Keywords: mesoionic heterocyclic; recent advances; advances mesoionic; heterocyclic olefins

Journal Title: Dalton transactions
Year Published: 2022

Link to full text (if available)


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