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Within the reaction of a metastable Ge(I)Cl solution and Na2Fe2(CO)8 the anionic cubic cluster compound {(thf)14Na6Ge8[Fe(CO)4]8}- (3) is obtained. The open shell character of 3 is proven by EPR spectroscopy.… Click to show full abstract
Within the reaction of a metastable Ge(I)Cl solution and Na2Fe2(CO)8 the anionic cubic cluster compound {(thf)14Na6Ge8[Fe(CO)4]8}- (3) is obtained. The open shell character of 3 is proven by EPR spectroscopy. Quantum chemical calculations furthermore show that also the closed shell systems should be stable, but could not be isolated so far. Additionally, 3 can be seen as an intermediate cluster compound on the formation of metalloid clusters.
Keywords:
iron cluster;
germanium iron;
cubic germanium;
cluster;
ge8 anionic;
anionic cubic
Journal Title: Dalton transactions
Year Published: 2022
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Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
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recommendations!