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Construction of a chiral zinc-camphorate framework for enantioselective separation.

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A chiral metal-organic framework (CMOF) with open chiral channels and multiple recognition sites is constructed from camphoric acid and a dipyridyl ligand. It can act as an efficient chiral solid… Click to show full abstract

A chiral metal-organic framework (CMOF) with open chiral channels and multiple recognition sites is constructed from camphoric acid and a dipyridyl ligand. It can act as an efficient chiral solid adsorbent, capable of separating a variety of racemic alcohols and epoxides with excellent enantioselectivities.

Keywords: framework enantioselective; zinc camphorate; camphorate framework; framework; construction chiral; chiral zinc

Journal Title: Dalton transactions
Year Published: 2022

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