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Toughening and stabilizing MOF crystals via polymeric guest inclusion.

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Improving the mechanical properties and stability of metal-organic frameworks (MOFs) is of significant interest due to their practical applications. Herein, we tune the mechanical properties of MOFs by filling the… Click to show full abstract

Improving the mechanical properties and stability of metal-organic frameworks (MOFs) is of significant interest due to their practical applications. Herein, we tune the mechanical properties of MOFs by filling the MOF pores with polymer chains. The mechanical properties reflect the filling rate, molecular weight, and inherent flexibility of the polymeric guests, imparting MOFs with improved resilience and toughness against mechanical pressures.

Keywords: mof crystals; stabilizing mof; via polymeric; mechanical properties; toughening stabilizing; crystals via

Journal Title: Dalton transactions
Year Published: 2022

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