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A well-defined thiolate-bridged cobalt-ruthenium complex is demonstrated to reversibly bind N2 by modulation of the auxiliary phosphine ligand, which is evidenced by time-dependent 1H NMR spectroscopy at different temperatures. Notably,… Click to show full abstract
A well-defined thiolate-bridged cobalt-ruthenium complex is demonstrated to reversibly bind N2 by modulation of the auxiliary phosphine ligand, which is evidenced by time-dependent 1H NMR spectroscopy at different temperatures. Notably, this heterobimetallic system represents the first example that can realize N2 coordination on a sulfur-rich Co-Ru cooperative scaffold.
Keywords:
cobalt ruthenium;
bridged cobalt;
phosphine ligand;
ruthenium complex;
thiolate bridged
Journal Title: Dalton transactions
Year Published: 2022
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Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!