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Solid-state and solution-phase characterization of SmII-aza[2.2.2]cryptate and its methylated analogue.

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Two new SmII-azacryptates are reported that differ in steric hindrance and Lewis basicity of donor atoms. The sterically hindered complex has a smaller coordination number and a more negative electrochemical… Click to show full abstract

Two new SmII-azacryptates are reported that differ in steric hindrance and Lewis basicity of donor atoms. The sterically hindered complex has a smaller coordination number and a more negative electrochemical potential than the complex with less steric hindrance.

Keywords: characterization smii; state solution; solution phase; solid state; phase characterization; smii

Journal Title: Dalton transactions
Year Published: 2022

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