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The U(V) imido complex (C5Me5)2UVI(NSiMe3), 1, was crystallographically characterized from the reaction of (C5Me5)2UIIII(THF) with N3SiMe3 which demonstrates that it can be an intermediate in the reaction which ultimately forms… Click to show full abstract
The U(V) imido complex (C5Me5)2UVI(NSiMe3), 1, was crystallographically characterized from the reaction of (C5Me5)2UIIII(THF) with N3SiMe3 which demonstrates that it can be an intermediate in the reaction which ultimately forms (C5Me5)2UVI(NSiMe3)2 and (C5Me5)2UIVI2. U(V) intermediates have been proposed in such reactions, but have not been previously observed. The direct observation of 1 provides insight into the reaction mechanisms of U(III) compounds with azide reagents.
Keywords:
c5me5;
reaction;
reaction c5me5;
2uvi nsime3;
c5me5 2uvi;
complex c5me5
Journal Title: Dalton transactions
Year Published: 2022
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Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
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recommendations!