LAUSR

The structural design of multiple functional components could enhance the synergistic catalytic performance of MoS2-based composites in enzyme-like catalysis. Herein, one-dimensional (1D) Fe-MoS2 microtubes were designed to prepare tubular Fe-doped MoS2 composites with MoO3 microrods as self-sacrificing precursors. Remarkably, the results indicated that the generated ammonia released from the sulfidation process led to the dissolution of MoO3 cores and the generation of a tubular structure. The Fe-MoS2 composites integrated the synergistic effects of Fe-doped MoS2 nanosheets (NSs) and the 1D tubular structure. Thus, a higher catalytic activity was observed in peroxidase-like catalysis than in other components, such as MoO3@FeOOH, FeOOH and MoS2 NSs. The peroxidase-like mechanism originated from the generation of the ˙OH radical. The Fe-MoS2 microtube-based colorimetric assay was used to detect H2O2 with a detection limit (LOD) of 0.51 μM in a linear range from 1.25 to 50 μM. The colorimetric method was simple, selective, and sensitive for glutathione (GSH) detection in the range of 0.25-125 μM with a detection limit (LOD) of 0.12 μM. Thus, we provide a facile synthetic strategy for simultaneously integrating electronic modulation and structural design to develop an efficient MoS2-based functional catalyst.