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Regioselective di- and tetrabrominations of the (B,O)2-perylene 1 afford derivatives 2-4. Despite their poor solubility, 2 and 4 could be used in Stille-type coupling reactions to introduce two CCMe (5)… Click to show full abstract
Regioselective di- and tetrabrominations of the (B,O)2-perylene 1 afford derivatives 2-4. Despite their poor solubility, 2 and 4 could be used in Stille-type coupling reactions to introduce two CCMe (5) or four CC(p-C6H4tBu) substituents (6), respectively. The alkynylated derivatives show blue-green photoluminescence with appreciable quantum efficiencies.
Keywords:
doped perylene;
derivatization doped;
late stage;
stage derivatization
Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!