Introducing sulfonic acid groups into MOF materials is one of the effective approaches to enhance proton conduction. Here, we attempted to prepare a new post-modified ZIF-90-based material by addition reaction… Click to show full abstract
Introducing sulfonic acid groups into MOF materials is one of the effective approaches to enhance proton conduction. Here, we attempted to prepare a new post-modified ZIF-90-based material by addition reaction of the aldehyde group with bisulfite to obtain partially functionalized ZIF-90-SO3Na(2.3). ZIF-90-SO3Na(2.3) exhibits a high proton conductivity of 2.26 × 10-2 S cm-1 at 98% RH and 100 °C.
               
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