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Photogenerated carrier behavior at a gas-solid interface for CO2 adsorption on Cs2AgBiBr6 nanocrystals.

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Photogenerated carrier behavior at a CO2/Cs2AgBiBr6 quantum dot (QD) interface is investigated. In situ photovoltage spectra reveal electron transfer from the Cs2AgBiBr6 QDs to CO2. Moreover, this carrier transfer prefers… Click to show full abstract

Photogenerated carrier behavior at a CO2/Cs2AgBiBr6 quantum dot (QD) interface is investigated. In situ photovoltage spectra reveal electron transfer from the Cs2AgBiBr6 QDs to CO2. Moreover, this carrier transfer prefers Bi3+ sites (over Ca+ and Ag+ sites) due to them exhibiting the lowest adsorption energy (Eads = -0.125 eV) and CO2-Bi3+ interactions being more stable.

Keywords: photogenerated carrier; carrier; carrier behavior; co2; cs2agbibr6

Journal Title: Dalton transactions
Year Published: 2022

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