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We report di- and trinuclear palladium sandwich complexes of cross-π-conjugated fulvenes. Structural and theoretical analysis revealed that a fulvene sandwich framework holds a metal-metal bonded moiety, where the dinuclear and… Click to show full abstract
We report di- and trinuclear palladium sandwich complexes of cross-π-conjugated fulvenes. Structural and theoretical analysis revealed that a fulvene sandwich framework holds a metal-metal bonded moiety, where the dinuclear and trinuclear bonds feature strong donation and back-donation, respectively. The trinuclear fulvene sandwich complex undergoes a unique reversible extrusion of a Pd atom from inside to outside the sandwich framework.
Keywords:
sandwich;
trinuclear sandwich;
sandwich complexes;
cross conjugated;
complexes cross
Journal Title: Dalton transactions
Year Published: 2023
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Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!