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A 2D Dy-based metal-organic framework derived from benzothiadiazole: structure and photocatalytic properties.

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A 2D Dy(III) metal-organic layer (MOL 1) was synthesized under solvothermal conditions. Structural analysis suggests that the Dy(III) ions in each one-dimensional (1D) arrangement are evenly arranged in the form… Click to show full abstract

A 2D Dy(III) metal-organic layer (MOL 1) was synthesized under solvothermal conditions. Structural analysis suggests that the Dy(III) ions in each one-dimensional (1D) arrangement are evenly arranged in the form of broken lines. The 1D chains are linked to one another via ligands to form a 2D layer that generates a 2D surface with elongated apertures. The photocatalytic activity study suggests that MOL 1 exhibits good catalytic activity in flavonoids by the formation of an O2˙- radical as an intermediate. This is the first reported method of synthesizing flavonoids using chalcones.

Keywords: organic framework; derived benzothiadiazole; metal organic; framework derived; based metal; metal

Journal Title: Dalton transactions
Year Published: 2023

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