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Herein, we report a twisted cubic Cu(I)4Ti(IV)4-oxo cluster stabilized by in situ - formed 2,2'-biphenolate ligands from the oxidative coupling of phenols. The 2,2'-biphenolate-functionalized Cu(I)4Ti(IV)4O4 cluster shows short Cu⋯C contacts… Click to show full abstract
Herein, we report a twisted cubic Cu(I)4Ti(IV)4-oxo cluster stabilized by in situ - formed 2,2'-biphenolate ligands from the oxidative coupling of phenols. The 2,2'-biphenolate-functionalized Cu(I)4Ti(IV)4O4 cluster shows short Cu⋯C contacts and exhibits smaller HOMO-LUMO gaps than those of reported Ti(IV)4O4.
Keywords:
oxidative coupling;
coupling phenols;
ligands oxidative;
biphenolate ligands;
cu4ti4 oxo
Journal Title: Dalton transactions
Year Published: 2023
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Journal Title: Dalton transactions
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!