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Enantioselective Meerwein-Ponndorf-Verley Reduction of β,γ-Unsaturated α-Keto Esters by Asymmetric Binary-Acid Catalysis in Green Solvent iPrOH

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Enantioselective Meerwein-Ponndorf-Verley reduction of β,γ-unsaturated α-keto esters in iPrOH alone was achieved by using asymmetric binary-acid catalysts. The presence of 0.2 mol% of a chiral phosphoric acid and 0.5 mol%... Click to show full abstract

Enantioselective Meerwein-Ponndorf-Verley reduction of β,γ-unsaturated α-keto esters in iPrOH alone was achieved by using asymmetric binary-acid catalysts. The presence of 0.2 mol% of a chiral phosphoric acid and 0.5 mol%...

Keywords: enantioselective meerwein; reduction unsaturated; ponndorf verley; acid; verley reduction; meerwein ponndorf

Journal Title: Green Chemistry
Year Published: 2023

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