Enantioselective Meerwein-Ponndorf-Verley reduction of β,γ-unsaturated α-keto esters in iPrOH alone was achieved by using asymmetric binary-acid catalysts. The presence of 0.2 mol% of a chiral phosphoric acid and 0.5 mol%... Click to show full abstract
Enantioselective Meerwein-Ponndorf-Verley reduction of β,γ-unsaturated α-keto esters in iPrOH alone was achieved by using asymmetric binary-acid catalysts. The presence of 0.2 mol% of a chiral phosphoric acid and 0.5 mol%...
               
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