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Assignment of the Absolute Configuration of Secondary Alcohols by 13C NMR and its Correlation with Methyl-1-(chloromethyl)-oxopyrrolidine-2-carboxylate and Quantum-Mechanical GIAO Calculations

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Analysis of the effect of steric compression on the chemical shifts of carbons (13C NMR) in diastereoisomers is an accessible strategy for assigning the absolute configuration of secondary alcohols. Here... Click to show full abstract

Analysis of the effect of steric compression on the chemical shifts of carbons (13C NMR) in diastereoisomers is an accessible strategy for assigning the absolute configuration of secondary alcohols. Here...

Keywords: absolute configuration; secondary alcohols; assignment absolute; configuration secondary; 13c nmr

Journal Title: New Journal of Chemistry
Year Published: 2023

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