An Au4Ni2 nanocluster containing a square-planar [-PPh2-Au-S-Au-]2 ring and two nickel-pincer arms is reported here. Abundant intra- and inter-cluster noncovalent interactions promote the assembly of the nanocluster into a porous… Click to show full abstract
An Au4Ni2 nanocluster containing a square-planar [-PPh2-Au-S-Au-]2 ring and two nickel-pincer arms is reported here. Abundant intra- and inter-cluster noncovalent interactions promote the assembly of the nanocluster into a porous framework material. The assembly-dependent unique solubility and photoluminescence were also investigated.
               
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