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Structure and assembly of a hexanuclear AuNi bimetallic nanocluster.

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An Au4Ni2 nanocluster containing a square-planar [-PPh2-Au-S-Au-]2 ring and two nickel-pincer arms is reported here. Abundant intra- and inter-cluster noncovalent interactions promote the assembly of the nanocluster into a porous… Click to show full abstract

An Au4Ni2 nanocluster containing a square-planar [-PPh2-Au-S-Au-]2 ring and two nickel-pincer arms is reported here. Abundant intra- and inter-cluster noncovalent interactions promote the assembly of the nanocluster into a porous framework material. The assembly-dependent unique solubility and photoluminescence were also investigated.

Keywords: hexanuclear auni; auni bimetallic; assembly hexanuclear; bimetallic nanocluster; structure assembly

Journal Title: Nanoscale
Year Published: 2022

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