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Structural engineering of BiOBr nanosheets for boosted photodegradation performance toward rhodamine B

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A series of BiOBr nanosheets were synthesized through a facile solvothermal method, whose structures were adjusted by changing solvent ratios. Their photodegradation properties toward rhodamine B (RhB) were further investigated… Click to show full abstract

A series of BiOBr nanosheets were synthesized through a facile solvothermal method, whose structures were adjusted by changing solvent ratios. Their photodegradation properties toward rhodamine B (RhB) were further investigated under visible light irradiation. The photocatalytic results indicated that the B-1:3 sample showed superior photoactivity and the RhB removal efficiency attained 97% within 30 min. The outstanding photodegradation activity can be ascribed to the small particle size and thickness, suppressed e−–h+ pair recombination and more active electrons and holes. Moreover, free radical quenching experiments suggest that ·O2− and h+ play a crucial role in improving photoactivity. This work opens a new avenue to boost the removal rate of organic pollutants by engineering the solvent ratios of photocatalysts in the wastewater treatment field.

Keywords: biobr nanosheets; toward rhodamine; structural engineering; photodegradation

Journal Title: RSC Advances
Year Published: 2022

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