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Investigation of the structural, electrical, and dielectric properties of La0.5Sm0.2Sr0.3Mn1−xCrxO3 for electrical application

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In the present research, polycrystalline samples of La0.5Sm0.2Sr0.3Mn1−xCrxO3 are prepared using the self-combustion method. Then, we have studied their crystalline structure, and dielectric and electrical properties. The X-ray diffraction study… Click to show full abstract

In the present research, polycrystalline samples of La0.5Sm0.2Sr0.3Mn1−xCrxO3 are prepared using the self-combustion method. Then, we have studied their crystalline structure, and dielectric and electrical properties. The X-ray diffraction study shows that all the samples exhibit a single phase with orthorhombic structure (space group Pnma). The studied samples were also characterized by complex impedance spectroscopy in a wide range of temperatures and frequency. AC conductivity analyses are used to study the transport property of the investigated samples. These analyses indicate that the conduction mechanism is strongly dependent on temperature and frequency. It is also found that the conductivity decreases with Cr concentration. Complex impedance analysis confirms the contributions of grain and grain boundaries in the conduction mechanism. Finally, the impedance spectra, characterized by the appearance of semicircle arcs at different temperatures, were well modeled in terms of equivalent electrical circuits to explain the impedance results.

Keywords: structural electrical; 2sr0 3mn1; 3mn1 xcrxo3; investigation structural; 5sm0 2sr0; la0 5sm0

Journal Title: RSC Advances
Year Published: 2022

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