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Barium molybdate white emitting phosphor synthesized at room temperature by co-precipitation

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Crystalline BaMoO4:Dy3+ and BaMoO4:Sm3+ phosphors were synthesized by co-precipitation at room temperature. The main peak (112) phase and tetragonal structure were confirmed using X-ray diffraction analysis. The lattice constant and… Click to show full abstract

Crystalline BaMoO4:Dy3+ and BaMoO4:Sm3+ phosphors were synthesized by co-precipitation at room temperature. The main peak (112) phase and tetragonal structure were confirmed using X-ray diffraction analysis. The lattice constant and Raman signal on d(112) were changed by the rare earth doping. A strong absorption wavelength appeared in the UV region, and BaMoO4:Dy3+ excited with UV wavelength showed a yellow spectrum. BaMoO4:Sm3+ showed a reddish orange spectrum. BaMoO4:[Sm3+]/[Dy3+] was synthesized for use as a white light phosphor, and the change in the emission characteristics of yellow, white, and reddish orange could be observed depending on the doping concentration of Sm3+ ions. The synthesized phosphor powder and PDMS polymer were mixed to form a flexible composite, and when applied on a UV-LED chip, the same color as the powder was realized, suggesting its use as an LED color filter.

Keywords: phosphor; sm3; bamoo4; room temperature; precipitation

Journal Title: RSC Advances
Year Published: 2022

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