Metal–organic framework-derived materials are now considered potential next-generation electrode materials for supercapacitors. In this present investigation, Co3O4@MnO2 nanosheets are synthesized using ZIF-67, which is used as a sacrificial template through… Click to show full abstract
Metal–organic framework-derived materials are now considered potential next-generation electrode materials for supercapacitors. In this present investigation, Co3O4@MnO2 nanosheets are synthesized using ZIF-67, which is used as a sacrificial template through a facile hydrothermal method. The unique vertically grown nanosheets provide an effective pathway for rapidly transporting electrons and ions. As a result, the ZIF-67 derived Co3O4@MnO2-3 electrode material shows a high specific capacitance of 768 C g−1 at 1 A g−1 current density with outstanding cycling stability (86% retention after 5000 cycles) and the porous structure of the material has a good BET surface area of 160.8 m2 g−1. As a hybrid supercapacitor, Co3O4@MnO2-3//activated carbon exhibits a high specific capacitance (82.9 C g−1) and long cycle life (85.5% retention after 5000 cycles). Moreover, a high energy density of 60.17 W h kg−1 and power density of 2674.37 W kg−1 has been achieved. This attractive performance reveals that Co3O4@MnO2 nanosheets could find potential applications as an electrode material for high-performance hybrid supercapacitors.
               
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