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The stable “F–SO2+” donor provides a mild and efficient approach to nitriles and amides

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In this update, we developed a mild, efficient and practical method using fluorosulfuryl imidazolium salt A as an environment friendly promoter for conversion of oximes to nitriles or amides via… Click to show full abstract

In this update, we developed a mild, efficient and practical method using fluorosulfuryl imidazolium salt A as an environment friendly promoter for conversion of oximes to nitriles or amides via β-elimination or Beckmann rearrangement in almost quantitative yield in 10 minutes. The target products were generated in gram-scale and could be collected through crystallization without silica gel column purification in excellent yield.

Keywords: so2 donor; nitriles amides; provides mild; mild efficient; stable so2; donor provides

Journal Title: RSC Advances
Year Published: 2022

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